ChemicalResistance
ChemicalResistance.org

PVC Rigid vs ECTFE/ETFE: Chemical Resistance Compared

Of 302 source rows rated for both materials at 20 °C, 173 (57 %) have the same rating. PVC Rigid is rated better in 6 rows and ECTFE/ETFE in 123. A row is one chemical at one concentration.

Summary

ECTFE/ETFE is rated better with
Halogenated hydrocarbons (+92 points); Esters and ethers (+90 points); Ketones and aldehydes (+89 points); Amines and nitrogen compounds (+77 points); Alcohols and glycols (+21 points); Mineral acids (+18 points); Fuels, mineral oils and aliphatic hydrocarbons (+16 points); Oxidising agents and halogens (+15 points); Organic acids (+13 points)
Within 10 points of each other
Alkalis; Salts and salt solutions; Foods and beverages

Points are the difference in the share of rows rated A or B.

The two materials

PVC Rigid

Rigid (unplasticised) polyvinyl chloride

Rigid PVC resists acids, alkalis and salt solutions well. Ketones, esters, aromatic and chlorinated solvents dissolve or swell it. Service temperature is limited to about 60 °C.

Rated rows: 569. A 62 %, B 8 %, C 9 %, D 21 %

All chemicals for PVC Rigid

ECTFE/ETFE

Ethylene chlorotrifluoroethylene / ethylene tetrafluoroethylene

ECTFE and ETFE are tough fluoropolymers with broad resistance. Hot amines and some chlorinated solvents at elevated temperature are their main limits.

Rated rows: 374. A 94 %, B 6 %, C 0 %, D 0 %

All chemicals for ECTFE/ETFE

Share of rows rated A or B, by chemical class

PVC Rigid, ECTFE/ETFE: Share of rows rated A or B, by chemical classMineral acids: PVC Rigid 82 %, ECTFE/ETFE 100 %. Organic acids: PVC Rigid 87 %, ECTFE/ETFE 100 %. Alkalis: PVC Rigid 100 %, ECTFE/ETFE 100 %. Salts and salt solutions: PVC Rigid 100 %, ECTFE/ETFE 100 %. Oxidising agents and halogens: PVC Rigid 85 %, ECTFE/ETFE 100 %. Alcohols and glycols: PVC Rigid 79 %, ECTFE/ETFE 100 %. Ketones and aldehydes: PVC Rigid 11 %, ECTFE/ETFE 100 %. Esters and ethers: PVC Rigid 5 %, ECTFE/ETFE 95 %. Amines and nitrogen compounds: PVC Rigid 23 %, ECTFE/ETFE 100 %. Fuels, mineral oils and aliphatic hydrocarbons: PVC Rigid 84 %, ECTFE/ETFE 100 %. Halogenated hydrocarbons: PVC Rigid 8 %, ECTFE/ETFE 100 %. Foods and beverages: PVC Rigid 100 %, ECTFE/ETFE 100 %.Mineral acidsMineral acids, PVC Rigid: 82 % (56)82 %Mineral acids, ECTFE/ETFE: 100 % (37)100 %Organic acidsOrganic acids, PVC Rigid: 87 % (45)87 %Organic acids, ECTFE/ETFE: 100 % (33)100 %AlkalisAlkalis, PVC Rigid: 100 % (16)100 %Alkalis, ECTFE/ETFE: 100 % (14)100 %Salts and salt solutionsSalts and salt solutions, PVC Rigid: 100 % (111)100 %Salts and salt solutions, ECTFE/ETFE: 100 % (114)100 %Oxidising agents and halogensOxidising agents and halogens, PVC Rigid: 85 % (39)85 %Oxidising agents and halogens, ECTFE/ETFE: 100 % (17)100 %Alcohols and glycolsAlcohols and glycols, PVC Rigid: 79 % (43)79 %Alcohols and glycols, ECTFE/ETFE: 100 % (25)100 %Ketones and aldehydesKetones and aldehydes, PVC Rigid: 11 % (18)11 %Ketones and aldehydes, ECTFE/ETFE: 100 % (14)100 %Esters and ethersEsters and ethers, PVC Rigid: 5 % (39)5 %Esters and ethers, ECTFE/ETFE: 95 % (20)95 %Amines and nitrogen compoundsAmines and nitrogen compounds, PVC Rigid: 23 % (22)23 %Amines and nitrogen compounds, ECTFE/ETFE: 100 % (9)100 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, PVC Rigid: 84 % (38)84 %Fuels, mineral oils and aliphatic hydrocarbons, ECTFE/ETFE: 100 % (13)100 %Halogenated hydrocarbonsHalogenated hydrocarbons, PVC Rigid: 8 % (36)8 %Halogenated hydrocarbons, ECTFE/ETFE: 100 % (16)100 %Foods and beveragesFoods and beverages, PVC Rigid: 100 % (23)100 %Foods and beverages, ECTFE/ETFE: 100 % (26)100 %
PVC RigidECTFE/ETFE
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

PVC Rigid, ECTFE/ETFE: How often the two ratings agreePVC Rigid A, ECTFE/ETFE A: 172; PVC Rigid A, ECTFE/ETFE B: 6; PVC Rigid B, ECTFE/ETFE A: 38; PVC Rigid C, ECTFE/ETFE A: 24; PVC Rigid C, ECTFE/ETFE B: 1; PVC Rigid C, ECTFE/ETFE C: 1; PVC Rigid D, ECTFE/ETFE A: 46; PVC Rigid D, ECTFE/ETFE B: 14.ECTFE/ETFEABCDPVC RigidAPVC Rigid A, ECTFE/ETFE A: 172172PVC Rigid A, ECTFE/ETFE B: 66PVC Rigid A, ECTFE/ETFE C: 00PVC Rigid A, ECTFE/ETFE D: 00BPVC Rigid B, ECTFE/ETFE A: 3838PVC Rigid B, ECTFE/ETFE B: 00PVC Rigid B, ECTFE/ETFE C: 00PVC Rigid B, ECTFE/ETFE D: 00CPVC Rigid C, ECTFE/ETFE A: 2424PVC Rigid C, ECTFE/ETFE B: 11PVC Rigid C, ECTFE/ETFE C: 11PVC Rigid C, ECTFE/ETFE D: 00DPVC Rigid D, ECTFE/ETFE A: 4646PVC Rigid D, ECTFE/ETFE B: 1414PVC Rigid D, ECTFE/ETFE C: 00PVC Rigid D, ECTFE/ETFE D: 00
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classPVC Rigid: rated A or BECTFE/ETFE: rated A or B
Mineral acids82 % (56 rows)100 % (37 rows)
Organic acids87 % (45 rows)100 % (33 rows)
Alkalis100 % (16 rows)100 % (14 rows)
Salts and salt solutions100 % (111 rows)100 % (114 rows)
Oxidising agents and halogens85 % (39 rows)100 % (17 rows)
Alcohols and glycols79 % (43 rows)100 % (25 rows)
Phenols38 % (8 rows)–
Ketones and aldehydes11 % (18 rows)100 % (14 rows)
Esters and ethers5 % (39 rows)95 % (20 rows)
Amines and nitrogen compounds23 % (22 rows)100 % (9 rows)
Aromatic hydrocarbons0 % (9 rows)–
Fuels, mineral oils and aliphatic hydrocarbons84 % (38 rows)100 % (13 rows)
Vegetable and animal oils, fats, essential oils59 % (17 rows)–
Halogenated hydrocarbons8 % (36 rows)100 % (16 rows)
Foods and beverages100 % (23 rows)100 % (26 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 84 in total, the first 40 shown.

ChemicalConcentrationPVC RigidECTFE/ETFE
1,2-DichlorobenzeneDA
1,4-DichlorobenzeneDA
AcetamidesaturatedDA
AcetonitrileDA
AcetophenoneDA
AcrylonitrileDA
AlanineDA
Amyl AcetateDA
Amyl ChlorideDA
Aqua RegiaDA
BenzaldehydeDA
BenzeneDA
Benzyl AcetateDA
Bitter Almond OilDA
Butyl Acetate100 %DA
Butyl Acrylate100 %DA
CarbazoleDA
Carbon DisulfideDA
Carbon TetrachlorideDA
ChlorobenzeneDA
Chloroethane (Ethyl Chloride)DA
Cinnamon OilDA
CresolDA
CumeneDA
Dibutyl Phthalate (DBP)DA
Diethyl Ethertechnical gradeDA
DiethylbenzeneDA
Dimethyl Sulfoxide (DMSO)DA
Ethyl Acetate100 %DA
Ethyl BenzoateDA
Ethyl ButyrateDA
Ethylene DichlorideDA
Iodine TinctureDA
Isopropyl AcetateDA
Methoxyethyl OleateDA
Methyl Propyl Ketone (2-Pentanone)DA
NitrobenzeneDA
p-ChloroacetophenoneDA
Perchloroethylene (PCE)DA
Phenol100 %DA

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is PVC Rigid or ECTFE/ETFE more chemical-resistant?

Of 302 chemicals rated for both materials at 20 °C, PVC Rigid and ECTFE/ETFE share the same rating in 173 rows (57 %). PVC Rigid is rated better in 6 rows and ECTFE/ETFE in 123 rows.

How do PVC Rigid and ECTFE/ETFE compare for chemical resistance?

Based on 302 chemicals tested for both: PVC Rigid is rated better with –. ECTFE/ETFE is rated better with Halogenated hydrocarbons, Esters and ethers, Ketones and aldehydes, Amines and nitrogen compounds. They perform similarly with Alkalis, Salts and salt solutions, Foods and beverages.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.