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PVC Rigid vs FEP: Chemical Resistance Compared

Of 545 source rows rated for both materials at 20 °C, 339 (62 %) have the same rating. PVC Rigid is rated better in 4 rows and FEP in 202. A row is one chemical at one concentration.

Summary

FEP is rated better with
Aromatic hydrocarbons (+100 points); Esters and ethers (+95 points); Ketones and aldehydes (+89 points); Halogenated hydrocarbons (+82 points); Amines and nitrogen compounds (+77 points); Phenols (+62 points); Vegetable and animal oils, fats, essential oils (+41 points); Alcohols and glycols (+21 points); Mineral acids (+18 points); Fuels, mineral oils and aliphatic hydrocarbons (+16 points); Oxidising agents and halogens (+15 points); Organic acids (+13 points)
Within 10 points of each other
Alkalis; Salts and salt solutions; Foods and beverages

Points are the difference in the share of rows rated A or B.

The two materials

PVC Rigid

Rigid (unplasticised) polyvinyl chloride

Rigid PVC resists acids, alkalis and salt solutions well. Ketones, esters, aromatic and chlorinated solvents dissolve or swell it. Service temperature is limited to about 60 °C.

Rated rows: 569. A 62 %, B 8 %, C 9 %, D 21 %

All chemicals for PVC Rigid

FEP

Fluorinated ethylene propylene

FEP has nearly the chemical resistance of PTFE and can be melt-processed. Its service temperature, about 200 °C, is lower than that of PTFE.

Rated rows: 908. A 99 %, B 0 %, C 1 %, D 0 %

All chemicals for FEP

Share of rows rated A or B, by chemical class

PVC Rigid, FEP: Share of rows rated A or B, by chemical classMineral acids: PVC Rigid 82 %, FEP 100 %. Organic acids: PVC Rigid 87 %, FEP 100 %. Alkalis: PVC Rigid 100 %, FEP 100 %. Salts and salt solutions: PVC Rigid 100 %, FEP 100 %. Oxidising agents and halogens: PVC Rigid 85 %, FEP 100 %. Alcohols and glycols: PVC Rigid 79 %, FEP 100 %. Phenols: PVC Rigid 38 %, FEP 100 %. Ketones and aldehydes: PVC Rigid 11 %, FEP 100 %. Esters and ethers: PVC Rigid 5 %, FEP 100 %. Amines and nitrogen compounds: PVC Rigid 23 %, FEP 100 %. Aromatic hydrocarbons: PVC Rigid 0 %, FEP 100 %. Fuels, mineral oils and aliphatic hydrocarbons: PVC Rigid 84 %, FEP 100 %. Vegetable and animal oils, fats, essential oils: PVC Rigid 59 %, FEP 100 %. Halogenated hydrocarbons: PVC Rigid 8 %, FEP 90 %. Foods and beverages: PVC Rigid 100 %, FEP 100 %.Mineral acidsMineral acids, PVC Rigid: 82 % (56)82 %Mineral acids, FEP: 100 % (55)100 %Organic acidsOrganic acids, PVC Rigid: 87 % (45)87 %Organic acids, FEP: 100 % (64)100 %AlkalisAlkalis, PVC Rigid: 100 % (16)100 %Alkalis, FEP: 100 % (18)100 %Salts and salt solutionsSalts and salt solutions, PVC Rigid: 100 % (111)100 %Salts and salt solutions, FEP: 100 % (197)100 %Oxidising agents and halogensOxidising agents and halogens, PVC Rigid: 85 % (39)85 %Oxidising agents and halogens, FEP: 100 % (52)100 %Alcohols and glycolsAlcohols and glycols, PVC Rigid: 79 % (43)79 %Alcohols and glycols, FEP: 100 % (57)100 %PhenolsPhenols, PVC Rigid: 38 % (8)38 %Phenols, FEP: 100 % (14)100 %Ketones and aldehydesKetones and aldehydes, PVC Rigid: 11 % (18)11 %Ketones and aldehydes, FEP: 100 % (33)100 %Esters and ethersEsters and ethers, PVC Rigid: 5 % (39)5 %Esters and ethers, FEP: 100 % (69)100 %Amines and nitrogen compoundsAmines and nitrogen compounds, PVC Rigid: 23 % (22)23 %Amines and nitrogen compounds, FEP: 100 % (38)100 %Aromatic hydrocarbonsAromatic hydrocarbons, PVC Rigid: 0 % (9)0 %Aromatic hydrocarbons, FEP: 100 % (14)100 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, PVC Rigid: 84 % (38)84 %Fuels, mineral oils and aliphatic hydrocarbons, FEP: 100 % (74)100 %Vegetable and animal oils, fats, essential oilsVegetable and animal oils, fats, essential oils, PVC Rigid: 59 % (17)59 %Vegetable and animal oils, fats, essential oils, FEP: 100 % (47)100 %Halogenated hydrocarbonsHalogenated hydrocarbons, PVC Rigid: 8 % (36)8 %Halogenated hydrocarbons, FEP: 90 % (49)90 %Foods and beveragesFoods and beverages, PVC Rigid: 100 % (23)100 %Foods and beverages, FEP: 100 % (46)100 %
PVC RigidFEP
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

PVC Rigid, FEP: How often the two ratings agreePVC Rigid A, FEP A: 339; PVC Rigid A, FEP B: 1; PVC Rigid B, FEP A: 40; PVC Rigid B, FEP C: 3; PVC Rigid C, FEP A: 48; PVC Rigid D, FEP A: 110; PVC Rigid D, FEP B: 3; PVC Rigid D, FEP C: 1.FEPABCDPVC RigidAPVC Rigid A, FEP A: 339339PVC Rigid A, FEP B: 11PVC Rigid A, FEP C: 00PVC Rigid A, FEP D: 00BPVC Rigid B, FEP A: 4040PVC Rigid B, FEP B: 00PVC Rigid B, FEP C: 33PVC Rigid B, FEP D: 00CPVC Rigid C, FEP A: 4848PVC Rigid C, FEP B: 00PVC Rigid C, FEP C: 00PVC Rigid C, FEP D: 00DPVC Rigid D, FEP A: 110110PVC Rigid D, FEP B: 33PVC Rigid D, FEP C: 11PVC Rigid D, FEP D: 00
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classPVC Rigid: rated A or BFEP: rated A or B
Mineral acids82 % (56 rows)100 % (55 rows)
Organic acids87 % (45 rows)100 % (64 rows)
Alkalis100 % (16 rows)100 % (18 rows)
Salts and salt solutions100 % (111 rows)100 % (197 rows)
Oxidising agents and halogens85 % (39 rows)100 % (52 rows)
Alcohols and glycols79 % (43 rows)100 % (57 rows)
Phenols38 % (8 rows)100 % (14 rows)
Ketones and aldehydes11 % (18 rows)100 % (33 rows)
Esters and ethers5 % (39 rows)100 % (69 rows)
Amines and nitrogen compounds23 % (22 rows)100 % (38 rows)
Aromatic hydrocarbons0 % (9 rows)100 % (14 rows)
Fuels, mineral oils and aliphatic hydrocarbons84 % (38 rows)100 % (74 rows)
Vegetable and animal oils, fats, essential oils59 % (17 rows)100 % (47 rows)
Halogenated hydrocarbons8 % (36 rows)90 % (49 rows)
Foods and beverages100 % (23 rows)100 % (46 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 161 in total, the first 40 shown.

ChemicalConcentrationPVC RigidFEP
1,2-DichlorobenzeneDA
1,4-DichlorobenzeneDA
Acetaldehyde40 %DA
Acetaldehydetechnical gradeDA
AcetamidesaturatedDA
Acetic Anhydridetechnical gradeDA
AcetoneDA
AcetonitrileDA
AcrylonitrileDA
AlanineDA
Allyl Chloride100 %DA
Amyl AcetateDA
Amyl ChlorideDA
AnilineDA
BenzaldehydeDA
BenzeneDA
Benzyl AcetateDA
Benzyl Chloride100 %DA
Bitter Almond OilDA
BromobenzeneDA
Bromochloromethane100 %DA
BromoformDA
Bromomethanetechnical gradeDA
Butyl Acetate100 %DA
Butyl Acrylate100 %DA
Butyl Glycol100 %DA
CamphorDA
Camphor OilDA
CarbazoleDA
Carbon DisulfideDA
Carbon TetrachlorideDA
Chloral Hydratetechnical gradeDA
Chlorine97 %DA
Chlorine GasDA
ChlorobenzeneDA
Chloroethane (Ethyl Chloride)DA
Chloroethanoltechnical gradeDA
Chloroform100 %DA
Chloromethane (Methyl Chloride)technical gradeDA
Cinnamon OilDA

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is PVC Rigid or FEP more chemical-resistant?

Of 545 chemicals rated for both materials at 20 °C, PVC Rigid and FEP share the same rating in 339 rows (62 %). PVC Rigid is rated better in 4 rows and FEP in 202 rows.

How do PVC Rigid and FEP compare for chemical resistance?

Based on 545 chemicals tested for both: PVC Rigid is rated better with –. FEP is rated better with Aromatic hydrocarbons, Esters and ethers, Ketones and aldehydes, Halogenated hydrocarbons. They perform similarly with Alkalis, Salts and salt solutions, Foods and beverages.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.