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FEP vs PVDF: Chemical Resistance Compared

Of 893 source rows rated for both materials at 20 °C, 669 (75 %) have the same rating. FEP is rated better in 222 rows and PVDF in 2. A row is one chemical at one concentration.

Summary

FEP is rated better with
Ketones and aldehydes (+38 points); Esters and ethers (+36 points); Alkalis (+36 points); Phenols (+29 points); Amines and nitrogen compounds (+24 points); Halogenated hydrocarbons (+18 points); Oxidising agents and halogens (+13 points); Mineral acids (+13 points); Vegetable and animal oils, fats, essential oils (+12 points)
Within 10 points of each other
Organic acids; Salts and salt solutions; Alcohols and glycols; Aromatic hydrocarbons; Fuels, mineral oils and aliphatic hydrocarbons; Foods and beverages

Points are the difference in the share of rows rated A or B.

The two materials

FEP

Fluorinated ethylene propylene

FEP has nearly the chemical resistance of PTFE and can be melt-processed. Its service temperature, about 200 °C, is lower than that of PTFE.

Rated rows: 908. A 99 %, B 0 %, C 1 %, D 0 %

All chemicals for FEP

PVDF

Polyvinylidene fluoride

PVDF resists acids, halogens and hydrocarbons. Strong bases, amines, ketones and esters attack it. Service temperature is up to about 150 °C.

Rated rows: 944. A 73 %, B 15 %, C 10 %, D 2 %

All chemicals for PVDF

Share of rows rated A or B, by chemical class

FEP, PVDF: Share of rows rated A or B, by chemical classMineral acids: FEP 100 %, PVDF 87 %. Organic acids: FEP 100 %, PVDF 94 %. Alkalis: FEP 100 %, PVDF 64 %. Salts and salt solutions: FEP 100 %, PVDF 99 %. Oxidising agents and halogens: FEP 100 %, PVDF 87 %. Alcohols and glycols: FEP 100 %, PVDF 98 %. Phenols: FEP 100 %, PVDF 71 %. Ketones and aldehydes: FEP 100 %, PVDF 62 %. Esters and ethers: FEP 100 %, PVDF 64 %. Amines and nitrogen compounds: FEP 100 %, PVDF 76 %. Aromatic hydrocarbons: FEP 100 %, PVDF 100 %. Fuels, mineral oils and aliphatic hydrocarbons: FEP 100 %, PVDF 97 %. Vegetable and animal oils, fats, essential oils: FEP 100 %, PVDF 88 %. Halogenated hydrocarbons: FEP 90 %, PVDF 72 %. Foods and beverages: FEP 100 %, PVDF 98 %.Mineral acidsMineral acids, FEP: 100 % (55)100 %Mineral acids, PVDF: 87 % (61)87 %Organic acidsOrganic acids, FEP: 100 % (64)100 %Organic acids, PVDF: 94 % (64)94 %AlkalisAlkalis, FEP: 100 % (18)100 %Alkalis, PVDF: 64 % (22)64 %Salts and salt solutionsSalts and salt solutions, FEP: 100 % (197)100 %Salts and salt solutions, PVDF: 99 % (198)99 %Oxidising agents and halogensOxidising agents and halogens, FEP: 100 % (52)100 %Oxidising agents and halogens, PVDF: 87 % (62)87 %Alcohols and glycolsAlcohols and glycols, FEP: 100 % (57)100 %Alcohols and glycols, PVDF: 98 % (58)98 %PhenolsPhenols, FEP: 100 % (14)100 %Phenols, PVDF: 71 % (14)71 %Ketones and aldehydesKetones and aldehydes, FEP: 100 % (33)100 %Ketones and aldehydes, PVDF: 62 % (34)62 %Esters and ethersEsters and ethers, FEP: 100 % (69)100 %Esters and ethers, PVDF: 64 % (66)64 %Amines and nitrogen compoundsAmines and nitrogen compounds, FEP: 100 % (38)100 %Amines and nitrogen compounds, PVDF: 76 % (38)76 %Aromatic hydrocarbonsAromatic hydrocarbons, FEP: 100 % (14)100 %Aromatic hydrocarbons, PVDF: 100 % (14)100 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, FEP: 100 % (74)100 %Fuels, mineral oils and aliphatic hydrocarbons, PVDF: 97 % (72)97 %Vegetable and animal oils, fats, essential oilsVegetable and animal oils, fats, essential oils, FEP: 100 % (47)100 %Vegetable and animal oils, fats, essential oils, PVDF: 88 % (48)88 %Halogenated hydrocarbonsHalogenated hydrocarbons, FEP: 90 % (49)90 %Halogenated hydrocarbons, PVDF: 72 % (54)72 %Foods and beveragesFoods and beverages, FEP: 100 % (46)100 %Foods and beverages, PVDF: 98 % (46)98 %
FEPPVDF
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

FEP, PVDF: How often the two ratings agreeFEP A, PVDF A: 665; FEP A, PVDF B: 129; FEP A, PVDF C: 77; FEP A, PVDF D: 14; FEP B, PVDF A: 2; FEP B, PVDF C: 2; FEP C, PVDF C: 4.PVDFABCDFEPAFEP A, PVDF A: 665665FEP A, PVDF B: 129129FEP A, PVDF C: 7777FEP A, PVDF D: 1414BFEP B, PVDF A: 22FEP B, PVDF B: 00FEP B, PVDF C: 22FEP B, PVDF D: 00CFEP C, PVDF A: 00FEP C, PVDF B: 00FEP C, PVDF C: 44FEP C, PVDF D: 00DFEP D, PVDF A: 00FEP D, PVDF B: 00FEP D, PVDF C: 00FEP D, PVDF D: 00
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classFEP: rated A or BPVDF: rated A or B
Mineral acids100 % (55 rows)87 % (61 rows)
Organic acids100 % (64 rows)94 % (64 rows)
Alkalis100 % (18 rows)64 % (22 rows)
Salts and salt solutions100 % (197 rows)99 % (198 rows)
Oxidising agents and halogens100 % (52 rows)87 % (62 rows)
Alcohols and glycols100 % (57 rows)98 % (58 rows)
Phenols100 % (14 rows)71 % (14 rows)
Ketones and aldehydes100 % (33 rows)62 % (34 rows)
Esters and ethers100 % (69 rows)64 % (66 rows)
Amines and nitrogen compounds100 % (38 rows)76 % (38 rows)
Aromatic hydrocarbons100 % (14 rows)100 % (14 rows)
Fuels, mineral oils and aliphatic hydrocarbons100 % (74 rows)97 % (72 rows)
Vegetable and animal oils, fats, essential oils100 % (47 rows)88 % (48 rows)
Halogenated hydrocarbons90 % (49 rows)72 % (54 rows)
Foods and beverages100 % (46 rows)98 % (46 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 91 in total, the first 40 shown.

ChemicalConcentrationFEPPVDF
Acetaldehyde40 %AD
Acetaldehydetechnical gradeAD
Acetic Anhydridetechnical gradeAD
Chloral Hydratetechnical gradeAD
Chloroacetic AcidAD
Dimethylformamide (DMF)AD
FluorineAD
Oleum (Fuming Sulfuric Acid)10 % SO3AD
Sodium Hydroxide (Caustic Soda)1 %AD
Sodium Hydroxide (Caustic Soda)30 %AD
Sodium Hydroxide (Caustic Soda)50 %AD
Sulfur DioxideliquidAD
Sulfuric AcidfumingAD
Trichloroacetaldehyde100 %AD
5-HydroxymethylfurfuralAC
AcetoneAC
AcrylonitrileAC
Anise OilAC
Anisole100 %AC
Benzyl AcetateAC
Benzyl Chloride100 %AC
Brake FluidAC
Bromochloromethane100 %AC
ButyraldehydeAC
CamphorAC
Camphor OilAC
Chloramine-TdiluteAC
CreosoteAC
Dichloroisopropyl EtherAC
Diethyl KetoneAC
Diethyl MalonateAC
Dimethyl Sulfoxide (DMSO)AC
Dimethylaminetechnical gradeAC
DioxaneAC
Epichlorohydrin100 %AC
Essential OilsAC
Ethyl Acetate100 %AC
Ethyl Acrylate100 %AC
Ethyl BenzoateAC
Ethyl CyanoacetateAC

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is FEP or PVDF more chemical-resistant?

Of 893 chemicals rated for both materials at 20 °C, FEP and PVDF share the same rating in 669 rows (75 %). FEP is rated better in 222 rows and PVDF in 2 rows.

How do FEP and PVDF compare for chemical resistance?

Based on 893 chemicals tested for both: FEP is rated better with Ketones and aldehydes, Esters and ethers, Alkalis, Phenols. PVDF is rated better with –. They perform similarly with Organic acids, Salts and salt solutions, Alcohols and glycols, Aromatic hydrocarbons.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.