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PMP vs FEP: Chemical Resistance Compared

Of 400 source rows rated for both materials at 20 °C, 224 (56 %) have the same rating. PMP is rated better in 0 rows and FEP in 176. A row is one chemical at one concentration.

Summary

FEP is rated better with
Aromatic hydrocarbons (+90 points); Halogenated hydrocarbons (+87 points); Vegetable and animal oils, fats, essential oils (+71 points); Fuels, mineral oils and aliphatic hydrocarbons (+70 points); Esters and ethers (+64 points); Ketones and aldehydes (+63 points); Amines and nitrogen compounds (+50 points); Oxidising agents and halogens (+33 points); Mineral acids (+29 points); Organic acids (+15 points)
Within 10 points of each other
Alkalis; Salts and salt solutions; Alcohols and glycols; Foods and beverages

Points are the difference in the share of rows rated A or B.

The two materials

PMP

Polymethylpentene (TPX)

Polymethylpentene (TPX) is a transparent polyolefin used for labware. It resists many acids and alkalis, while aromatic and chlorinated solvents and strong oxidisers attack it.

Rated rows: 416. A 55 %, B 6 %, C 7 %, D 32 %

All chemicals for PMP

FEP

Fluorinated ethylene propylene

FEP has nearly the chemical resistance of PTFE and can be melt-processed. Its service temperature, about 200 °C, is lower than that of PTFE.

Rated rows: 908. A 99 %, B 0 %, C 1 %, D 0 %

All chemicals for FEP

Share of rows rated A or B, by chemical class

PMP, FEP: Share of rows rated A or B, by chemical classMineral acids: PMP 71 %, FEP 100 %. Organic acids: PMP 85 %, FEP 100 %. Alkalis: PMP 100 %, FEP 100 %. Salts and salt solutions: PMP 100 %, FEP 100 %. Oxidising agents and halogens: PMP 67 %, FEP 100 %. Alcohols and glycols: PMP 96 %, FEP 100 %. Ketones and aldehydes: PMP 37 %, FEP 100 %. Esters and ethers: PMP 36 %, FEP 100 %. Amines and nitrogen compounds: PMP 50 %, FEP 100 %. Aromatic hydrocarbons: PMP 10 %, FEP 100 %. Fuels, mineral oils and aliphatic hydrocarbons: PMP 30 %, FEP 100 %. Vegetable and animal oils, fats, essential oils: PMP 29 %, FEP 100 %. Halogenated hydrocarbons: PMP 3 %, FEP 90 %. Foods and beverages: PMP 100 %, FEP 100 %.Mineral acidsMineral acids, PMP: 71 % (35)71 %Mineral acids, FEP: 100 % (55)100 %Organic acidsOrganic acids, PMP: 85 % (26)85 %Organic acids, FEP: 100 % (64)100 %AlkalisAlkalis, PMP: 100 % (17)100 %Alkalis, FEP: 100 % (18)100 %Salts and salt solutionsSalts and salt solutions, PMP: 100 % (67)100 %Salts and salt solutions, FEP: 100 % (197)100 %Oxidising agents and halogensOxidising agents and halogens, PMP: 67 % (30)67 %Oxidising agents and halogens, FEP: 100 % (52)100 %Alcohols and glycolsAlcohols and glycols, PMP: 96 % (28)96 %Alcohols and glycols, FEP: 100 % (57)100 %Ketones and aldehydesKetones and aldehydes, PMP: 37 % (27)37 %Ketones and aldehydes, FEP: 100 % (33)100 %Esters and ethersEsters and ethers, PMP: 36 % (42)36 %Esters and ethers, FEP: 100 % (69)100 %Amines and nitrogen compoundsAmines and nitrogen compounds, PMP: 50 % (10)50 %Amines and nitrogen compounds, FEP: 100 % (38)100 %Aromatic hydrocarbonsAromatic hydrocarbons, PMP: 10 % (10)10 %Aromatic hydrocarbons, FEP: 100 % (14)100 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, PMP: 30 % (37)30 %Fuels, mineral oils and aliphatic hydrocarbons, FEP: 100 % (74)100 %Vegetable and animal oils, fats, essential oilsVegetable and animal oils, fats, essential oils, PMP: 29 % (14)29 %Vegetable and animal oils, fats, essential oils, FEP: 100 % (47)100 %Halogenated hydrocarbonsHalogenated hydrocarbons, PMP: 3 % (33)3 %Halogenated hydrocarbons, FEP: 90 % (49)90 %Foods and beveragesFoods and beverages, PMP: 100 % (13)100 %Foods and beverages, FEP: 100 % (46)100 %
PMPFEP
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

PMP, FEP: How often the two ratings agreePMP A, FEP A: 224; PMP B, FEP A: 26; PMP C, FEP A: 28; PMP C, FEP B: 1; PMP D, FEP A: 121.FEPABCDPMPAPMP A, FEP A: 224224PMP A, FEP B: 00PMP A, FEP C: 00PMP A, FEP D: 00BPMP B, FEP A: 2626PMP B, FEP B: 00PMP B, FEP C: 00PMP B, FEP D: 00CPMP C, FEP A: 2828PMP C, FEP B: 11PMP C, FEP C: 00PMP C, FEP D: 00DPMP D, FEP A: 121121PMP D, FEP B: 00PMP D, FEP C: 00PMP D, FEP D: 00
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classPMP: rated A or BFEP: rated A or B
Mineral acids71 % (35 rows)100 % (55 rows)
Organic acids85 % (26 rows)100 % (64 rows)
Alkalis100 % (17 rows)100 % (18 rows)
Salts and salt solutions100 % (67 rows)100 % (197 rows)
Oxidising agents and halogens67 % (30 rows)100 % (52 rows)
Alcohols and glycols96 % (28 rows)100 % (57 rows)
Phenols–100 % (14 rows)
Ketones and aldehydes37 % (27 rows)100 % (33 rows)
Esters and ethers36 % (42 rows)100 % (69 rows)
Amines and nitrogen compounds50 % (10 rows)100 % (38 rows)
Aromatic hydrocarbons10 % (10 rows)100 % (14 rows)
Fuels, mineral oils and aliphatic hydrocarbons30 % (37 rows)100 % (74 rows)
Vegetable and animal oils, fats, essential oils29 % (14 rows)100 % (47 rows)
Halogenated hydrocarbons3 % (33 rows)90 % (49 rows)
Foods and beverages100 % (13 rows)100 % (46 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 149 in total, the first 40 shown.

ChemicalConcentrationPMPFEP
1,2-DibromoethaneDA
1,3-ButadieneDA
1-PentanethiolDA
Acetic Anhydridetechnical gradeDA
Acetyl Chloride100 %DA
Allyl Acetate100 %DA
Allyl Chloride100 %DA
Allyl Mustard OilDA
Amyl ChlorideDA
Amyl CinnamaldehydeDA
Anise OilDA
Benzyl AlcoholDA
Benzyl Chloride100 %DA
BromineDA
Bromine VaporsDA
BromobenzeneDA
Bromochloromethane100 %DA
BromoformDA
ButyraldehydeDA
Butyric AcidDA
Carbon DisulfideDA
Carbon TetrachlorideDA
Cedar OilDA
Chlorine97 %DA
Chlorine GasDA
Chlorine WaterDA
ChlorobenzeneDA
ChlorobutadieneDA
Chloroform100 %DA
ChlorotolueneDA
CinnamaldehydeDA
Cinnamon OilDA
CresolDA
Crotonaldehydetechnical gradeDA
CumeneDA
CyclohexaneDA
CymeneDA
DecahydronaphthaleneDA
Dibutyl Ethertechnical gradeDA
Dichloroethylenetechnical gradeDA

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is PMP or FEP more chemical-resistant?

Of 400 chemicals rated for both materials at 20 °C, PMP and FEP share the same rating in 224 rows (56 %). PMP is rated better in 0 rows and FEP in 176 rows.

How do PMP and FEP compare for chemical resistance?

Based on 400 chemicals tested for both: PMP is rated better with –. FEP is rated better with Aromatic hydrocarbons, Halogenated hydrocarbons, Vegetable and animal oils, fats, essential oils, Fuels, mineral oils and aliphatic hydrocarbons. They perform similarly with Alkalis, Salts and salt solutions, Alcohols and glycols, Foods and beverages.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.