ChemicalResistance
ChemicalResistance.org

HDPE vs PVC Flexible: Chemical Resistance Compared

Of 314 source rows rated for both materials at 20 °C, 182 (58 %) have the same rating. HDPE is rated better in 128 rows and PVC Flexible in 4. A row is one chemical at one concentration.

Summary

HDPE is rated better with
Amines and nitrogen compounds (+90 points); Alcohols and glycols (+85 points); Ketones and aldehydes (+84 points); Esters and ethers (+69 points); Fuels, mineral oils and aliphatic hydrocarbons (+62 points); Mineral acids (+38 points); Organic acids (+35 points); Oxidising agents and halogens (+31 points)
Within 10 points of each other
Alkalis; Salts and salt solutions; Halogenated hydrocarbons; Foods and beverages

Points are the difference in the share of rows rated A or B.

The two materials

HDPE

High-density polyethylene

High-density polyethylene resists most aqueous acids, alkalis and salt solutions. Strong oxidising acids, chlorinated solvents and aromatic hydrocarbons attack or swell it. Continuous service is usually limited to about 80 °C.

Rated rows: 686. A 82 %, B 3 %, C 9 %, D 6 %

All chemicals for HDPE

PVC Flexible

Flexible (plasticised) polyvinyl chloride

Flexible PVC shares the solvent weaknesses of rigid PVC, and any liquid that extracts the plasticiser also hardens it. It is generally less resistant than rigid PVC.

Rated rows: 344. A 45 %, B 1 %, C 17 %, D 37 %

All chemicals for PVC Flexible

Share of rows rated A or B, by chemical class

HDPE, PVC Flexible: Share of rows rated A or B, by chemical classMineral acids: HDPE 79 %, PVC Flexible 41 %. Organic acids: HDPE 95 %, PVC Flexible 60 %. Alkalis: HDPE 100 %, PVC Flexible 100 %. Salts and salt solutions: HDPE 100 %, PVC Flexible 96 %. Oxidising agents and halogens: HDPE 78 %, PVC Flexible 47 %. Alcohols and glycols: HDPE 93 %, PVC Flexible 8 %. Ketones and aldehydes: HDPE 84 %, PVC Flexible 0 %. Esters and ethers: HDPE 73 %, PVC Flexible 4 %. Amines and nitrogen compounds: HDPE 90 %, PVC Flexible 0 %. Fuels, mineral oils and aliphatic hydrocarbons: HDPE 79 %, PVC Flexible 17 %. Halogenated hydrocarbons: HDPE 10 %, PVC Flexible 0 %. Foods and beverages: HDPE 100 %, PVC Flexible 93 %.Mineral acidsMineral acids, HDPE: 79 % (56)79 %Mineral acids, PVC Flexible: 41 % (27)41 %Organic acidsOrganic acids, HDPE: 95 % (58)95 %Organic acids, PVC Flexible: 60 % (25)60 %AlkalisAlkalis, HDPE: 100 % (22)100 %Alkalis, PVC Flexible: 100 % (11)100 %Salts and salt solutionsSalts and salt solutions, HDPE: 100 % (193)100 %Salts and salt solutions, PVC Flexible: 96 % (81)96 %Oxidising agents and halogensOxidising agents and halogens, HDPE: 78 % (40)78 %Oxidising agents and halogens, PVC Flexible: 47 % (17)47 %Alcohols and glycolsAlcohols and glycols, HDPE: 93 % (43)93 %Alcohols and glycols, PVC Flexible: 8 % (26)8 %Ketones and aldehydesKetones and aldehydes, HDPE: 84 % (19)84 %Ketones and aldehydes, PVC Flexible: 0 % (9)0 %Esters and ethersEsters and ethers, HDPE: 73 % (37)73 %Esters and ethers, PVC Flexible: 4 % (25)4 %Amines and nitrogen compoundsAmines and nitrogen compounds, HDPE: 90 % (21)90 %Amines and nitrogen compounds, PVC Flexible: 0 % (12)0 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, HDPE: 79 % (38)79 %Fuels, mineral oils and aliphatic hydrocarbons, PVC Flexible: 17 % (23)17 %Halogenated hydrocarbonsHalogenated hydrocarbons, HDPE: 10 % (31)10 %Halogenated hydrocarbons, PVC Flexible: 0 % (31)0 %Foods and beveragesFoods and beverages, HDPE: 100 % (32)100 %Foods and beverages, PVC Flexible: 93 % (14)93 %
HDPEPVC Flexible
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

HDPE, PVC Flexible: How often the two ratings agreeHDPE A, PVC Flexible A: 147; HDPE A, PVC Flexible B: 4; HDPE A, PVC Flexible C: 45; HDPE A, PVC Flexible D: 46; HDPE B, PVC Flexible A: 2; HDPE B, PVC Flexible C: 1; HDPE B, PVC Flexible D: 7; HDPE C, PVC Flexible A: 2; HDPE C, PVC Flexible C: 6; HDPE C, PVC Flexible D: 25; HDPE D, PVC Flexible D: 29.PVC FlexibleABCDHDPEAHDPE A, PVC Flexible A: 147147HDPE A, PVC Flexible B: 44HDPE A, PVC Flexible C: 4545HDPE A, PVC Flexible D: 4646BHDPE B, PVC Flexible A: 22HDPE B, PVC Flexible B: 00HDPE B, PVC Flexible C: 11HDPE B, PVC Flexible D: 77CHDPE C, PVC Flexible A: 22HDPE C, PVC Flexible B: 00HDPE C, PVC Flexible C: 66HDPE C, PVC Flexible D: 2525DHDPE D, PVC Flexible A: 00HDPE D, PVC Flexible B: 00HDPE D, PVC Flexible C: 00HDPE D, PVC Flexible D: 2929
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classHDPE: rated A or BPVC Flexible: rated A or B
Mineral acids79 % (56 rows)41 % (27 rows)
Organic acids95 % (58 rows)60 % (25 rows)
Alkalis100 % (22 rows)100 % (11 rows)
Salts and salt solutions100 % (193 rows)96 % (81 rows)
Oxidising agents and halogens78 % (40 rows)47 % (17 rows)
Alcohols and glycols93 % (43 rows)8 % (26 rows)
Phenols62 % (8 rows)–
Ketones and aldehydes84 % (19 rows)0 % (9 rows)
Esters and ethers73 % (37 rows)4 % (25 rows)
Amines and nitrogen compounds90 % (21 rows)0 % (12 rows)
Aromatic hydrocarbons33 % (9 rows)–
Fuels, mineral oils and aliphatic hydrocarbons79 % (38 rows)17 % (23 rows)
Vegetable and animal oils, fats, essential oils71 % (21 rows)–
Halogenated hydrocarbons10 % (31 rows)0 % (31 rows)
Foods and beverages100 % (32 rows)93 % (14 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 100 in total, the first 40 shown.

ChemicalConcentrationHDPEPVC Flexible
Acetic Acid90 %AD
Acetylene100 %AD
AcrylonitrileAD
Allyl Alcohol96 %AD
Amyl AcetateAD
AnilineAD
BenzaldehydeAD
Bitter Almond OilAD
Butanoltechnical gradeAD
Butyl Acrylate100 %AD
Calcium Chloridealcoholic solutionAD
Chloroacetic AcidAD
CreosoteAD
Cyclohexanoltechnical gradeAD
Cyclohexanonetechnical gradeAD
Dibutyl Phthalate (DBP)AD
Dibutyl Sebacatetechnical gradeAD
Dimethylaminetechnical gradeAD
Epichlorohydrin100 %AD
Ethyl Acetate100 %AD
Ethylenediaminetechnical gradeAD
Formamidetechnical gradeAD
Furfuryl Alcoholtechnical gradeAD
Iodine TinctureAD
Methyl Isobutyl Ketone (MIBK)AD
Isooctanetechnical gradeAD
Isopropyl AcetateAD
Isopropanoltechnical gradeAD
Methyl Acetatetechnical gradeAD
Methyl Ethyl Ketone (MEK)AD
Methyl Glycol100 %AD
Methylamine32 %AD
Morpholinetechnical gradeAD
NaphthaAD
Nitrotoluenetechnical gradeAD
Picric Acid1 % aqueousAD
Potassium CyanidesaturatedAD
PropeneAD
Propionic AcidAD
PyridineAD

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is HDPE or PVC Flexible more chemical-resistant?

Of 314 chemicals rated for both materials at 20 °C, HDPE and PVC Flexible share the same rating in 182 rows (58 %). HDPE is rated better in 128 rows and PVC Flexible in 4 rows.

How do HDPE and PVC Flexible compare for chemical resistance?

Based on 314 chemicals tested for both: HDPE is rated better with Amines and nitrogen compounds, Alcohols and glycols, Ketones and aldehydes, Esters and ethers. PVC Flexible is rated better with –. They perform similarly with Alkalis, Salts and salt solutions, Halogenated hydrocarbons, Foods and beverages.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.